文献类型：期刊文献

英文题名：F5PhSeSePhF5 as a novel and versatile photosensitive reagent for the low-energy green light-induced seleno-Michael addition reaction

作者：Shi, Haoliang;Zhu, Yifei;Zhang, Yongqiang[1]

机构：[1]East China Univ Sci & Technol, Shanghai Frontiers Sci Ctr Optogenet Tech Cell Met, Shanghai Key Lab New Drug Design, Shanghai 200237, Peoples R China; East China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China

年份：2025

卷号：23

期号：36

起止页码：8176

外文期刊名：ORGANIC & BIOMOLECULAR CHEMISTRY

收录：;EI(收录号：20253819197602);WOS:【SCI-EXPANDED(收录号:WOS:001563087100001)，CCR-EXPANDED(收录号:WOS:001563087100001)】；

基金：Financial support from the program of the National Natural Science Foundation of China (22171080 and 22471072, Y.-Q. Z.) and the Natural Science Foundation of Shanghai Municipality (23ZR1417200, Y.-Q. Z.) is gratefully acknowledged.

语种：英文

外文关键词：Fluorine compounds - Light sensitive materials - Photosensitivity - Reagents - Rhenium compounds - Selenium compounds

摘要：Herein, we wish to report the discovery of a photosensitive diselenide reagent F5PhSeSePhF5, which could be activated by low-energy green light and transformed into selenol via a photoredox process for the Michael addition. Furthermore, this strategy could be extended to other types of nucleophilic reactions, enabling the facile synthesis of structurally diverse selenides.