详细信息
悬浮结晶法预处理敌草胺生产废水
Pretreatment of napropamide production wastewater by suspension crystallization method
文献类型:期刊文献
中文题名:悬浮结晶法预处理敌草胺生产废水
英文题名:Pretreatment of napropamide production wastewater by suspension crystallization method
作者:陈晓远[1];闫莹[1];范成李[1];刘勰[1];刘勇弟[1];张乐华[1]
机构:[1]华东理工大学资源与环境工程学院国家环境保护化工过程环境风险评价与控制重点实验室,上海200237
年份:2019
卷号:39
期号:2
起止页码:163
中文期刊名:化工环保
外文期刊名:Environmental Protection of Chemical Industry
收录:CSTPCD;;北大核心:【北大核心2017】;CSCD:【CSCD_E2019_2020】;
语种:中文
中文关键词:悬浮结晶;冰晶;钾离子;敌草胺;废水处理
外文关键词:suspension crystallization;ice crystal;potassium ion;napropamide;wastewater treatment
摘要:采用悬浮结晶法对敌草胺生产废水进行焚烧前预处理,研究了不同成冰率条件下废水的处理效果,并对冷冻过程中的析出晶体进行了表征。在成冰率为61.3%时,出水COD、色度和电导率的去除率分别可达94.0%、99.2%和89.1%。出水pH为9~10,满足后续生化处理的pH要求。在成冰率为61.3%时,一级浓缩液热值较原水增加了129%,且焚烧量大幅下降。析出晶体的主要组分为KCl和脂肪族酰胺。在成冰率为61.3%时,每处理1 t原水可回收89 kg析出晶体,具有较好的资源化利用前景。
The napropamide production wastewater was pretreated before combustion by suspension crystallization method. The treatment effects of the wastewater under different ice formation rates were studied,and the precipitated crystals in the freezing process were characterized. When the ice formation rate was 61.3%,the removal rates of COD, chroma and conductivity of the effluent were 94.0%,99.2% and 89.1%,respectively. The effluent pH was 9-10, which met the pH requirement of follow-up biochemical treatment. When the ice formation rate was 61.3%,the heat value of the first-grade concentrate increased by 129% compared with the initial wastewater,and the combustion amount decreased substantially. The main components of the precipitated crystals were KCl and aliphatic amides. When the ice formation rate was 61.3%,89 kg precipitated crystals was recovered from 1 ton initial wastewater,with a good prospect for resource utilization.
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