文献类型：期刊文献

英文题名：Investigation of the microstructure, cation distribution and optical properties of nanoscale NixMg1-xAl2O4 spinel pigments

作者：Yan, Jianghao[1];Huang, Jianguo[1];Zhang, Tao[1];Tian, Haoran[1];Yu, Jia[1];Zhang, Liyue[1];Zhang, Yuantao[1]

机构：[1]East China Univ Sci & Technol, Sch Mat Sci & Engn, 130 Meilong Rd, Shanghai, Peoples R China

年份：2019

卷号：45

期号：11

起止页码：14073

外文期刊名：CERAMICS INTERNATIONAL

收录：;EI(收录号：20191606802882);WOS:【SCI-EXPANDED(收录号:WOS:000471086200054)】；

基金：This work was supported by the Project of the National Natural Science Foundation of China (contract grant number 51872093 and 51672302).

语种：英文

外文关键词：Nanoscale; Spinel pigment; Rietveld refinement; Cation distribution

摘要：Nanoscale NixMg1-xAl2O4 spinel pigments were synthesized by a citric acid precursor combined with the gel-casting method. The microstructure, cation distribution and optical properties as a function of calcining temperature and nickel content were investigated by the X-ray diffraction (XRD) Rietveld refinement, transmission/field emission scanning electron microscopy (TEM/FESEM), X-ray photoelectron spectroscopy (XPS), colour measurement and UV-vis-NIR spectrophotometry. Upon increasing the calcining temperature, both Ni2+ and Mg2+ hindered the migration of Al3+ to octahedral sites. When the Ni content increased, the cation site percentage of Ni2+ in the tetrahedral and octahedral sites varied slightly while that of Al3+ and Mg2+ change substantially. The cation exchange resulted in an increase in the inversion parameters and a decrease in the lattice parameters with increasing temperature or Ni content. Furthermore, Rietveld refinement also showed a shrinkage of the tetrahedra and an expansion of the distorted octahedra in the spinel structure. Short-range information based on optical spectra suggests that variation in the splitting energy of tetrahedra and octahedra caused the change in the spectral absorption. This study may deepen the understanding of the structural-optical property relationship of NixMg1-xAl2O4 spinel, which is vital to the further colour modification of ceramics and glazes.