文献类型：期刊文献

英文题名：Highly sensitive detection of low-level water content in organic solvents and cyanide in aqueous media using novel solvatochromic AIEE fluorophores

作者：Chen, Wei[1,2];Zhang, Zhiyun[1,2];Li, Xin[3];Agren, Hans[3];Su, Jianhua[1,2]

机构：[1]E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China;[2]Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China;[3]KTH Royal Inst Technol, Div Theoret Chem & Biol, Sch Biotechnol, S-10691 Stockholm, Sweden

年份：2015

卷号：5

期号：16

起止页码：12191

外文期刊名：RSC ADVANCES

收录：;EI(收录号：20150600499434);WOS:【SCI-EXPANDED(收录号:WOS:000348985400064)】；

基金：This work was supported by NSFC/China and the National Basic Research 973 Program. X.L. and H.A. acknowledge computational resources provided by the Swedish National Infrastructure for Computing (SNIC 025/12-38).

语种：英文

外文关键词：Fluorescence - Potable water - Cyanides - Probes - Citrus fruits - Density functional theory

摘要：A great deal of effort has been devoted to develop easy-to-use fluorescent probes for detecting analytes due to their advantages in the field of chemo- and bio-sensing. Herein, two novel 2,2 '-biindenyl-based derivatives BDM and BDBM containing dicyanovinyl groups have been designed and synthesized, and are shown to possess the remarkable dual properties of solvatochromism and aggregation-induced emission enhancement (AIEE). Importantly, both of them are found to serve as fluorescent indicators for the qualitative and quantitative detection of low-level water in organic solvents. Meanwhile, both BDM and BDBM emit yellowish orange and orange fluorescence, respectively, in their aggregated states. Furthermore, with dicyanovinyl groups as the recognition sites, both compounds can act as colourimetric and fluorescent sensors for highly sensitive and selective detection of cyanide in aqueous media, and the apparent response signals can be observed by the naked eye even in the presence of various interference anions, promising practical applications for detecting cyanide in drinking water. Besides, optical spectroscopic techniques, NMR titration measurements, and density functional theory calculations are conducted to rationalize the sensing mechanisms of the two probes.