文献类型：期刊文献

中文题名：PE－AA辐射接枝共聚合的反应历程研究

英文题名：SOME INVESTIGATIONS ON THE NATURE OF REACTION PROCEEDING OF RADIATION INDUCED GRAFTING IN THE POLYETHYLENE-ACRYLIC ACID SYSTEM

作者：蒋歧康[1];孙宏斌[1];张志平[1]

机构：[1]中国纺织大学,上海高分子功能材料研究所,华东理工大学

年份：1995

卷号：13

期号：3

起止页码：161

中文期刊名：辐射研究与辐射工艺学报

外文期刊名：Journal of Radiation Research and Radiation Processing

收录：CSTPCD;;北大核心:【北大核心1992】；CSCD:【CSCD_E2011_2012】；

语种：中文

中文关键词：聚乙烯;丙烯酸;甲基丙烯酸;接枝共聚反应

外文关键词：Polyethylene, Acrylic acid, Methacrylic acid, Radiation, Surface grafting, Penetration grafting, Diffusion

摘要：研究了聚乙烯（ＰＥ）与丙烯酸（ＡＡ）、甲基丙烯酸（ＭＡＡ）的接枝共聚反应，探讨了接枝反应过程及特征：单体首先在ＰＥ表面接枝，然后进入内部进行本体接枝。研究表明：表面接枝为动力学控制，本体接技系扩散控制。
Direct radiation grafting of acrylic acid (AA) and methacrylic acid (MAA) onto polyethylene (PE) films were studied, The investigation of the nature and characters of grafting proceeding were performed. The penetration of grafting onto the thin PE film was studied and the mechanism discussed. This involevs an initial stage whereby the grafted surface layer deforms the PE allowing further monomer to penetrate. It was shown that the surface grafting was dynamic controlled and the penetration of monomer depended on the polarity of monomer.