文献类型：期刊文献

英文题名：Axially chiral C₂-symmetric N-heterocyclic carbene (NHC) palladium complexes-catalyzed asymmetric arylation of aldehydes with arylboronic acids

作者：Zhang, Rui[1,2];Xu, Qin[1,2];Zhang, Xiuchun[1,2];Zhang, Tao[1,2];Shi, Min[1,2,3]

机构：[1]E China Univ Sci & Technol, Sch Chem & Mol Engn, Key Lab Adv Mat, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Sch Chem & Mol Engn, Inst Fine Chem, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

年份：2010

卷号：21

期号：15

起止页码：1928

外文期刊名：TETRAHEDRON-ASYMMETRY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000281626300020)，CCR-EXPANDED(收录号:WOS:000281626300020)】；

基金：Financial support from the Shanghai Municipal Committee of Science and Technology (06XD14005 and 08dj1400100-2), the National Basic Research Program of China (973)-2010CB833302, and the National Natural Science Foundation of China (20902019, 20872162, 20672127, 20821002, 20732008 and 20702059) is greatly acknowledged.

语种：英文

摘要：Chiral C-2-symmetric N-heterocyclic carbene (NHC) palladium diaquo complexes 5a-c and the chiral C-2-symmetric NHC-palladium complexes 5d and 5e prepared from (R)-BINAM or H-8-(R)-BINAM could be used as the catalysts for the enantioselective arylation of arylaldehydes with arylboronic acids in which NHC-Pd complex 5a was found to be fairly effective in this reaction to give the corresponding adducts in moderate enantioselectivities along with moderate to good yields. (C) 2010 Elsevier Ltd. All rights reserved.