文献类型：期刊文献

中文题名：微波法合成新型双酚A二苯醚型双马来酰亚胺研究

英文题名：SYNTHESIS OF 4,4-DIPHENYL BISPHENOL A ETHER BISMALEIMIDE UNDER MICROWAVE IRRADIATION

作者：李鹏[1];张衍[1];刘育建[1];方俊[1]

机构：[1]华东理工大学材料科学与工程学院,特种功能高分子材料及其相关技术教育部重点实验室,上海200237

年份：2013

期号：5

起止页码：12

中文期刊名：玻璃钢／复合材料

外文期刊名：Fiber Reinforced Plastics/Composites

收录：北大核心:【北大核心2011】；CSCD:【CSCD_E2013_2014】；

基金：上海市重点学科资助(B502)

语种：中文

中文关键词：微波辐射;2,2'-双[4-(马来酰亚胺基苯氧基)苯基]丙烷;正交试验

外文关键词：microwave irradiation ; 2,2＇-bis [ 4- （4-maleimidophenox） phenyl ] propane ; orthogonal design

摘要：本文采用微波辐射方法,以顺丁烯二酸酐(MA)和2,2'-双[4-(4-氨基苯氧基)苯基]丙烷(BAPP)为原料,合成了2,2'-双[4-(马来酰亚胺基苯氧基)苯基]丙烷(BPA-BMI),并通过红外光谱、核磁共振、质谱等对产物结构进行表征。经过正交试验确定了微波法合成BPA-BMI的最佳工艺条件为n(MA)∶n(BAPP)=2.3∶1,催化剂用量为10%(wt%),辐射功率为450W,辐射时间为30min,产率可达67.26%。结果表明:与传统制备双马来酰亚胺的方法相比,微波法不仅可行,并且具有反应时间大大缩短、效率高、操作简单、环境友好等特点。
Using maleic anhydride and 2,2＇-bis [ 4- （4-aminophenox） phenyl ] propane as raw materials, a novel bismalemide monomer, 2,2＇-bis [ 4- （4-maleimidophenox） phenyl ] propane （BPA-BMI） was synthesized under microwave irradiation. The structure of compound was confirmed by FT-IR spectra, 1H-NMR and MS. On the basis of orthogonal design, the optimal preparation conditions for BPA-BMI under microwave irradiation was as follows ： the mola ratio of maleic anhydride to BAPP was 2. 3： 1, catalyst amount was 10% （wt%） , microwave power was 450W and radiation time was 30min. The highest yield of product was 67.26%. Compared with tradition preparation of BMI, the method of microwave irradiation is convenient, quick and less pollution.