文献类型：期刊文献

英文题名：Rational design and synthesis of a porous, task-specific polycarbazole for efficient CO2 capture

作者：Jin, Tian[1,2];Xiong, Yan[1,2];Zhu, Xiang[3];Tian, Ziqi[4];Tao, Duan-Jian[3];Hu, Jun[1,2];Jiang, De-en[4];Wang, Hualin[5];Liu, Honglai[1,2];Dai, Sheng[3,6]

机构：[1]E China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Dept Chem, Shanghai 200237, Peoples R China;[3]Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA;[4]Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA;[5]E China Univ Sci & Technol, State Environm Protect Key Lab Environm Risk Asse, Shanghai 200237, Peoples R China;[6]Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA

年份：2016

卷号：52

期号：24

起止页码：4454

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000372174700005)】；

基金：TJ, YX and HLL were supported by the National Key Technology Support Program of China (2015BAC04B01), the National Natural Science Foundation of China (No. 91334203, 21376074 and 21321064) and the 111 Project of Ministry of Education of China (No. B08021). XZ, ZT, DJ and SD were supported by the U.S. Department of Energy, Office of Science, Basic Energy Sciences, Chemical Sciences, Geosciences, and Biosciences Division.

语种：英文

摘要：We present a rational design and synthesis of a novel porous pyridine-functionalized polycarbazole for efficient CO2 capture based on the density functional theory calculations. The task-specific polymer, generated through a one-step FeCl3-catalyzed oxidative coupling reaction, exhibits a superior CO2 uptake at 1.0 bar and 273 K (5.57 mmol g(-1)).