文献类型：期刊文献

英文题名：Axially chiral BINIM and Ni(II)-catalyzed highly enantioselective 1,3-dipolar cycloaddition reactions of azomethine ylides and N-arylmaleimides

作者：Shi, Jing-Wen[1]; Zhao, Mei-Xin[1]; Lei, Zhi-Yu[1]; Shi, Min[1,2]

机构：[1] School of Chemistry and Molecular Engineering, East China University of Science and Technology, Laboratory for Advanced Materials, 130 Mei Long Road, Shanghai 200237, China; [2] State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China

年份：2008

卷号：73

期号：1

起止页码：305

外文期刊名：Journal of Organic Chemistry

收录：EI(收录号：20080211011288)

语种：英文

外文关键词：Bismuth compounds - Catalyst activity - Cycloaddition - Enantiomers - Enantioselectivity - Reaction kinetics

摘要：(Chemical Equation Presented) Axially chiral BINIM-Ni(II) complexes are effective catalysts in the asymmetric 1,3-dipolar cycloaddition reactions of azomethine ylides and N-arylmaleimides to give the corresponding adducts in good yields and up to 95% enantiomeric excesses. ? 2008 American Chemical Society.