文献类型：期刊文献

英文题名：A Decade of UiO-66 Research: A Historic Review of Dynamic Structure, Synthesis Mechanisms, and Characterization Techniques of an Archetypal Metal-Organic Framework

作者：Winarta, Joseph[1];Shan, Bohan[1];Mcintyre, Sean M.[1];Ye, Lei[1];Wang, Cheng[2];Liu, Jichang[2];Mu, Bin[1]

机构：[1]Arizona State Univ, Sch Engn Matter Transport & Energy, 501 East Tyler Mall, Tempe, AZ 85287 USA;[2]East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China

年份：2020

卷号：20

期号：2

起止页码：1347

外文期刊名：CRYSTAL GROWTH & DESIGN

收录：;EI(收录号：20200107971211);WOS:【SCI-EXPANDED(收录号:WOS:000512216600091)】；

基金：B.M. would like to acknowledge the National Science Foundation (Grant Number CMMI-1825594). J.L. acknowledges the joint fund by the National Natural Science Foundation of China and PetroChina (Project U1862204).

语种：英文

外文关键词：Organometallics - Crystalline materials - Thermogravimetric analysis - Metals - Economic and social effects

摘要：UiO-66 is an archetypal metal-organic framework (MOF) with a very high surface area as well as high thermal stability. It is found that the stability can be attributed to the metal oxide node being cuboctahedral allowing for 12 extension points for 1,4-benzenedicarboxylic acid (BDC) coordination. Because of this and its exceptional tunability and functionality, which are largely due to defect control of both missing-cluster and missing-linker defects, UiO-66 has gained scientific popularity. The combination of these characteristics allows for a highly versatile material that can be adapted to many different applications. The purpose for this work is to provide a historic overview of UiO-66, outlining the major developments that changed the synthesis strategies of Zr-based MOF as well as current and future works, which include defect control, aqueous crystallization, functionality-stability trade-offs, and advanced topographies. A breakdown of the various UiO-66 structures, including isoreticular and reo-type, and different characterization techniques such as powder X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric analysis, and nitrogen porosimetry are discussed as well.