文献类型：期刊文献

英文题名：Ce stabilized Ni-SrO as a catalytic phase transition sorbent for integrated CO2 capture and CH4 reforming

作者：Gu, Haiming[1,2];Gao, Yunfei[1,3];Iftikhar, Sherafghan[1];Li, Fanxing[1]

机构：[1]North Carolina State Univ, Dept Chem & Biomol Engn, Raleigh, NC 27695 USA;[2]Nanjing Inst Technol, Sch Energy & Power Engn, Nanjing 211167, Peoples R China;[3]East China Univ Sci & Technol, Shanghai Engn Res Ctr Coal Gasificat, Key Lab Coal Gasificat & Energy Chem Engn, Minist Educ, Shanghai 200237, Peoples R China

年份：2022

卷号：10

期号：6

起止页码：3077

外文期刊名：JOURNAL OF MATERIALS CHEMISTRY A

收录：;EI(收录号：20220711647245);WOS:【SCI-EXPANDED(收录号:WOS:000742160900001)】；

基金：This work was supported by the US National Science Foundation (CBET-1923468), the U.S. Department of Energy (EE0008809), and Kenan Institute of Engineering, Technology, and Science.

语种：英文

外文关键词：Efficiency - Flue gases - Sorption - Carbonation - Packed beds - Sintering - Binary alloys - Morphology - X ray diffraction - Sorbents - Thermodynamics - Cerium oxide - Nickel

摘要：Integration of carbon dioxide capture from flue gas with dry reforming of CH4 represents an attractive approach for CO2 utilization. The selection of a suitable bifunctional material serving as a catalyst/sorbent is the key. This paper reports Ni decorated and CeOx-stabilized SrO (SrCe0.5Ni0.5) as a multi-functional, phase transition catalytic sorbent material. The effect of CeOx on the morphology, structure, decarbonation reactivity, and cycling stability of the catalytic sorbent was determined with TEM-EDX, XRD, in situ XRD, CH4-TPR and TGA. Cyclic process tests were conducted in a packed bed reactor. The results indicate that large Ni clusters were present on the surface of the SrNi sorbent, and the addition of CeO2 promoted even distribution of Ni on the surface. Moreover, the Ce-Sr interaction promoted a complex carbonation/decarbonation phase-transition, i.e. SrCO3 + CeO2 <-> Sr2CeO4 + CO2 as opposed to the conventional, simple carbonation/decarbonation cycles (e.g. SrCO3 <-> SrO + CO2). This double replacement crystalline phase transition mechanism not only adjusts the carbonation/calcination thermodynamics to facilitate SrCO3 decomposition at relatively low temperatures but also inhibits sorbent sintering. As a result, excellent activity and stability were observed with up to 91% CH4 conversion, >72% CO2 capture efficiency and similar to 100% residual O-2 capture efficiency from flue gas by utilizing the CeO2 <-> Ce2O3 redox transition. This renders an intensified process with zero coke deposition. Moreover, the SLDRM with SrCe0.5Ni0.5 has the flexibility to produce concentrated CO via CO2-splitting while co-producing a syngas with tunable H-2/CO ratios.