文献类型：期刊文献

英文题名：Direct hydrogenolysis of biomass-derived furans over Pt/CeO2 catalyst with high activity and stability

作者：Tong, Tao[1];Xia, Qineng[1];Liu, Xiaohui[1];Wang, Yanqin[1]

机构：[1]East China Univ Sci & Technol, Shanghai Key Lab Funct Mat Chem, Res Inst Ind Catalysis, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China

年份：2017

卷号：101

起止页码：129

外文期刊名：CATALYSIS COMMUNICATIONS

收录：;EI(收录号：20173404075525);WOS:【SCI-EXPANDED(收录号:WOS:000411552400029)】；

基金：This work was supported financially by the NSFC of China (No. 91545103, 21603072 and 21403065), the Science and Technology Commission of Shanghai Municipality (10dz2220500), China Postdoctoral Science Foundation (2016M590328), and the Fundamental Research Funds for the Central Universities (222201714010).

语种：英文

外文关键词：Hydrogenolysis; Furfural; 1,2-Pentandiol; Pt/CeO2; Ring opening

摘要：Conversion of biomass -derived furans to fine chemicals has raised wide interests recently. Here we show direct hydrogenolysis of furans to corresponding alcohols in i-propanol (i-PrOH) over a highly active and stable Pt/CeO2 catalyst. CeO2 as the support shows superior catalytic performance in comparison to other supports. The hydrogenolysis of furfural to 1,2-pentandiol (1,2-PeD) can be realized in high yields (up to 59.9%) under mild conditions. Moreover, this catalytic system shows good recyclability with no obvious activity loss after five successive runs, which goes a step further towards the industrial application of heterogeneous catalysts for fine chemical production from biomass.