文献类型：期刊文献

英文题名：In Situ Synthesis of TS-1 on Carbon Nanotube Decorated Nickel Foam with Ultrafine Nanoparticles and High Content of Skeleton Titanium

作者：Zhang, Zheng[1];Kong, Xiao-Xin[1];Feng, Miao[1];Luo, Zhao-Hui[1];Lu, Hui[1];Cao, Gui-Ping[1]

机构：[1]East China Univ Sci & Technol, State Key Lab Chem Engn, UNILAB, Shanghai 200237, Peoples R China

年份：2019

卷号：58

期号：1

起止页码：69

外文期刊名：INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

收录：;EI(收录号：20190106336886);WOS:【SCI-EXPANDED(收录号:WOS:000455690400010)】；

基金：This work was financially supported by the National Natural Science Foundation of China (21576091).

语种：英文

外文关键词：Foams - Synthesis (chemical) - Nanoparticles - Titanium - Musculoskeletal system - Aluminum - Nickel

摘要：In this Article, TS-1 was successfully synthesized on carbon nanotubes decorated nickel foam via in situ strategy forming the monolithic TS-1 (MTS-1). To the best of our knowledge, situ synthesis of the MTS-1 has not been reported. Carbon nanotubes decorated nickel foam has many aggregated pores (confined pores formed in aggregated structure) and a large surface area, and TS-1 particles could be dispersed on the surface of CNT@NF. MTS-1 had the characteristics of ultrafine nanoparticle and high content of skeleton titanium. High absorptive property and electrostatic interaction between CNT@NF and gels could accelerate the crystallization rate. The TS-1 particles were solidly immobilized on the CNT@NF, and the conversion rate was almost constant even after multiple reactions. The catalyst is easy to separate from liquid products after reaction, which offers an economical application prospect.