文献类型：期刊文献

英文题名：Porous Metal-Organic Framework-Polymer Composites Using High Internal Phase Emulsion Templates: A Review

作者：Qiu, Yue[1];Li, Jin-Jin[1];Zhao, Ling[1];Xi, Zhenhao[1,2];Yuan, Weikang[1]

机构：[1]East China Univ Sci & Technol, Sch Chem Engn, State Key Lab Chem Engn, Shanghai 200237, Peoples R China;[2]Chinese Univ Sci & Technol, Shanghai Key Lab Multiphase Mat Chem Engn, Shanghai 200237, Peoples R China

年份：2022

卷号：41

期号：12

起止页码：2212060

外文期刊名：CHINESE JOURNAL OF STRUCTURAL CHEMISTRY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000909834600008)】；

基金：This work was supported by the National Natural Science Foundation of China (21808140, 21978089), Shanghai Rising-Star Program (22QA1402800), and the Fundamental Research Funds for the Central Universities. The authors would like to appreciate Professor Yin-Ning Zhou at Shanghai Jiao Tong University for his constructive suggestions and kind revision, as well as the guest editor Professor Yun-Xiang Pan at Shanghai Jiao Tong University for his invitation.

语种：英文

外文关键词：high internal phase emulsion (HIPE); metal-organic frameworks (MOFs); adsorption and separation; heterogeneous catalysis; bioengineering

摘要：As promising engineering materials for green and sustainable processes, porous metalorganic framework (MOF)-polymer composites show great potential in applications, including adsorption, separation, catalysis, and bioengineering. Owing to themild and scalable operation, porous polymeric materials derived from high internal phase emulsion templates (polyHIPE) have received great interests in recent decades. In this contribution, research progress of the preparation of porous MOF@polyHIPE composites and their applications are reviewed, highlighting how can MOF particles be shaped by HIPE templates, in particular the polymerizable ones. Four different emulsion templates stabilized by MOFs and the applications of corresponding MOF@polyHIPE are included. Hopefully, both the state-of-art and future directions present herein can give rise to the development of highperformance porous MOF@polyHIPEs.