文献类型：期刊文献

中文题名：Out-of-equilibrium supramolecular self-assembling systems driven by chemical fuel

作者：Qian Wang[1];Zhen Qi[1];Meng Chen[1];Da-Hui Qu[1]

机构：[1]Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering,Feringa Nobel Prize Scientist Joint Research Center,School of Chemistry and Molecular Engineering,East China University of Science and Technology,Shanghai,China

年份：2021

卷号：2

期号：5

起止页码：100

中文期刊名：Aggregate

外文期刊名：聚集体（英文）

基金：National Natural Science Foundation of China,Grant/Award Numbers:22025503,21790361,21871084,21672060;Shanghai Municipal Science and Technology Major Project,Grant/Award Number:2018SHZDZX03;Fundamental Research Funds for the Central Universities,the Programme of Introducing Talents of Discipline to Universities,Grant/Award Number:B16017;Program of Shanghai Academic/Technology Research Leader,Grant/Award Number:19XD1421100;Shanghai Science and Technology Committee,Grant/Award Number:17520750100。

语种：英文

中文关键词：chemical fuel;out-of-equilibrium;supramolecular chemistry

摘要：A rich variety of smart materials developed via supramolecular assembly strategies have been introduced in the past decades.However,most materials reside in the thermodynamic equilibrium state,opposed to those nonequilibrium structures with sophisticated functions that are observed in living systems.To develop advanced synthetic systems,chemists have begun to focus on how to use strategies similar to those used in biological systems for fabricating artificial out-of-equilibrium systems.Heretofore,a rich variety of artificial out-of-equilibrium systems have been developed.In this review,we have summarized the recent progress of artificial out-of-equilibrium systems and categorized them in terms of the chemical fuel used,including adenosine triphosphate(ATP),acid/base,carbodiimide reagents,and many others.For these self-assembling systems,their design strategies,potential applications,as well as advantageous features have been discussed.At the end of this review,the remaining challenges and an outlook of the chemical-fuel-driven out-of-equilibrium systems were also discussed.It is believed that this review has provided some insights and could be useful for those who are interested in the out-of-equilibrium supramolecular assembling systems and their subsequent constructing strategies for various transient materials.