文献类型：期刊文献

英文题名：Theory-guided design of atomic Fe-Ni dual sites in N,P-co-doped C for boosting oxygen evolution reaction

作者：Pan, Fenghongkang[1,2];Jin, Tian[3];Yang, Weiwei[1,2];Li, He[1,2];Cao, Yueqiang[4];Hu, Jun[1,2];Zhou, Xinggui[4];Liu, Honglai[1,2];Duan, Xuezhi[4]

机构：[1]East China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China;[2]East China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China;[3]Xi An Jiao Tong Univ, Sch Sci, Dept Appl Chem, MOE Key Lab Nonequilibrium Synth & Modulat Conden, Xian 710049, Peoples R China;[4]East China Univ Sci & Technol, Sch Chem Engn, State Key Lab Chem Engn, Shanghai 200237, Peoples R China

年份：2021

卷号：1

期号：3

起止页码：734

外文期刊名：CHEM CATALYSIS

收录：WOS:【ESCI(收录号:WOS:000901252100006)】；

基金：This work was supported by the Natural Science Foundation of China (nos. 91834301, 21676080, and 21878076) and the Science and Technology Commission of Shanghai Municipality (no.19160712100).

语种：英文

摘要：The principle of how the active sites of catalysts match the reaction intermediates has long been sought after. Herein, we report a theory- guided atomic design and fabrication strategy of a C-based catalyst with diatomic Fe-Ni and N, P co- doping for the oxygen evolution reaction ( OER). The configuration matching (with O* on the Ni site and OH* on the adjacent Fe site) and the local electron engineering by P doping significantly facilitate the rate-determining step of OOH* formation. Such diatomic Fe-Ni is demonstrated to be thermodynamically stable and is precisely constructed through the pyrolysis of Fe3+/Ni2+-adsorbed ZIF-8 under NaH2PO2 cofeeding. The synergistic effects endow the catalyst with a low overpotential and high turnover frequency, exceeding all transitionmetal N-based catalysts so far as we know, which provides a deep understanding of the OERmechanism on heteroatomicmetal-based catalysts. This strategy will pave the way for novel catalyst design and the replacement of noble- metal-based catalysts.