文献类型：期刊文献

中文题名：热处理对紫色翡翠光谱学特征影响的研究

英文题名：Influence on Spectral Characteristics of Purple Jade by Heat Treatment

作者：陈晨[1];郭守国[1];毛荐[1]

机构：[1]华东理工大学材料科学与工程学院,上海200237

年份：2010

卷号：47

期号：4

起止页码：85

中文期刊名：激光与光电子学进展

外文期刊名：Laser & Optoelectronics Progress

收录：CSTPCD;;Scopus;北大核心:【北大核心2008】；CSCD:【CSCD_E2011_2012】；

基金：超细材料制备与应用教育部重点实验室基金资助课题

语种：中文

中文关键词：紫色翡翠;氧化气氛热处理;X-射线衍射谱图;紫外-可见吸收光谱;拉曼光谱

外文关键词：purple jade; oxidation atmosphere heat treatment; X-ray diffraction pattern; ultraviolet visible absorption spectrum; Raman spectrum

摘要：使用X射线衍射仪(XRD)、紫外-可见吸收光谱仪(UV-VIS)与拉曼光谱仪,对进行氧化气氛热处理前后的紫色翡翠样品进行光谱测试。XRD分析结果显示,紫色翡翠样品中95%以上是硬玉成分。热处理前后的紫外-可见吸收光谱对比结果显示,样品热处理后的光谱和热处理前相比,437nm处尖峰以及580nm处吸收包基本消失;而拉曼光谱图对比结果显示,热处理后黄褐色部位拉曼峰值基线整体呈上升趋势。分析结果表明,紫色翡翠样品主要致色离子为Fe2+,在经过热处理后,Fe2+氧化成为Fe3+,生成Fe2O3,从而致使热处理后的紫色翡翠样品呈现出黄褐色。
Purple jade sample was tested before and after heat treatment under oxidational atmosphere with X-ray diffractometer（XRD）,ultraviolet visible（UV-VIS） absorption spectrosmeter and Raman spectrometer.XRD analysis results show that the major components of the sample are jadeite.The sample UV-VIS absorption spectra before and after heat treatment shows that after heat treatment the spikes at 437 nm and 580 nm almost disappear,while Raman spectra of purple jade brown section after heat treatment shows that the baseline presents rising trend.According to the above analysis,the following conclusion is drawn：the main color-causing ion is Fe2＋,while Fe2＋ changes to Fe3＋ after heat treatment and Fe2O3 is formed.Therefore the sample of purple jade shows brown after the heat treatment.