文献类型：期刊文献

英文题名：Photocatalytic Hydrogen Production from Pure Water Using a IEF-11/g-C3N4 S-Scheme Heterojunction

作者：Qian, An[1];Han, Xin[1];Liu, Qiaona[1];Fan, Minwei[1];Ye, Lei[1];Pu, Xin[1];Chen, Ying[2];Liu, Jichang[1,3];Sun, Hui[1];Zhao, Jigang[1];Ling, Hao[1];Wang, Rongjie[3];Li, Jiangbing[3];Jia, Xin[3]

机构：[1]East China Univ Sci & Technol, Sch Chem Engn, Shanghai 200237, Peoples R China;[2]SINOPEC Shanghai Engn Co Ltd SSEC, Shanghai 200120, Peoples R China;[3]Shihezi Univ, Sch Chem & Chem Engn, State Key Lab Incubat Base Green Proc Chem Engn, Shihezi 832003, Peoples R China

年份：2024

卷号：17

期号：6

外文期刊名：CHEMSUSCHEM

收录：;EI(收录号：20240815587974);WOS:【SCI-EXPANDED(收录号:WOS:001167105100001)】；

基金：This project received financial support from the National Natural Science Foundation of China (No.: 22108074, 22008070).

语种：英文

外文关键词：MOF; g-C3N4; S-scheme heterojunction; Water splitting; Hydrogen production

摘要：Construction of S-scheme heterojunction offers a promising way to enhance the photocatalytic performance of photocatalysts for converting solar energy into chemical energy. However, the photocatalytic H-2 production in pure water without sacrificial agents is still a challenge. Herein, the IEF-11 with the best photocatalytic H-2 production performance in MOFs and suitable band structure was selected and firstly constructed with g-C3N4 to obtain a S-scheme heterojunction for photocatalytic H-2 production from pure water. As a result, the novel IEF-11/g-C3N4 heterojunction photocatalysts exhibited significantly improved photocatalytic H-2 production performance in pure water without any sacrificial agent, with a rate of 576 mu mol/g/h, which is about 8 times than that of g-C3N4 and 23 times of IEF-11. The novel IEF-11/g-C3N4 photocatalysts also had a photocatalytic H-2 production rate of up to 92 mu mol/g/h under visible light and a good photocatalytic stability. The improved performance can be attributed to the efficient separation of photogenerated charge carriers, faster charge transfer efficiency and longer photogenerated carrier lifetimes, which comes from the forming of S-scheme heterojunction in the IEF-11/g-C3N4 photocatalyst. This work is a promising guideline for obtaining MOF-based or g-C3N4-based photocatalysts with great photocatalytic water splitting performance.