文献类型：期刊文献

英文题名：Tetranuclear nickel(II) complex with tripodal hydroxyl ligand functionalized by additional salicylaldehyde donor pendant: Synthesis, crystal structure and magnetic property

作者：Ran, Jing-Wen[1,2];Zhang, Su-Yun[1];Xu, Bin[2];Xia, Yuanzhi[2];Guo, Dong[3];Zhang, Jing-Yan[4];Li, Yahong[1,2]

机构：[1]Suzhou Univ, Coll Chem & Chem Engn, Key Lab Organ Sythesis Jiangsu Prov, Suzhou 215123, Peoples R China;[2]Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China;[3]Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China;[4]E China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China

年份：2008

卷号：11

期号：1

起止页码：73

外文期刊名：INORGANIC CHEMISTRY COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000253105200019)】；

语种：英文

外文关键词：tetranuclear; cubane-like; nickel complex; magnetic properties

摘要：The tetranuclear cubane-like [Ni-4(H(3)hbhpd)(4)] center dot 4H(2)O complex has been prepared by the reaction of nickel(II) acetate with H(5)hbhpd, where H5hbhpd is 2(2-hydroxy-benzylamino)-2-hydroxymethyl-propane-1,3-diol. The X-ray diffraction analysis of the complex showed a Ni4O4 cubane arrangement of four nickel atoms. Magnetic studies indicate ferromagnetic behavior for the complex. The magnetic data were fitted and the parameters are given as g = 2.21, J(1) = 0.32, J(2) = 8.27, D = -0.05 cm(-1). (c) 2007 Elsevier B.V. All rights reserved.