文献类型：期刊文献

英文题名：Metal-Free Cross-Coupling of Arylboronic Acids and Derivatives with DAST-Type Reagents for Direct Access to Diverse Aromatic Sulfinamides and Sulfonamides

作者：Wang, Qiang[1,2];Tang, Xiang-Ying[3];Shi, Min[1,2,3]

机构：[1]East China Univ Sci & Technol, Key Lab Adv Mat, Meilong Rd 130, Shanghai 200237, Peoples R China;[2]East China Univ Sci & Technol, Inst Fine Chem, Meilong Rd 130, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai Inst Organ Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China

年份：2016

卷号：55

期号：36

起止页码：10811

外文期刊名：ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

收录：;EI(收录号：20163502756198);WOS:【SCI-EXPANDED(收录号:WOS:000383473600052)，CCR-EXPANDED(收录号:WOS:000383473600052)】；

基金：We are grateful for the financial support of the National Basic Research Program of China (973; 2015CB856603) and the National Natural Science Foundation of China (20472096, 21372241, 21361140350, 20672127, 21421091, 21372250, 21121062, 21302203, 20732008, and 21572052).

语种：英文

外文关键词：arylboronic acids; cross-coupling; sulfinamides; sulfonamides; synthetic methods

摘要：We have developed a simple and convenient method for the cross-coupling of arylboronic acids and their derivatives with DAST-type reagents under mild and metal-free conditions to directly afford sulfinamides in moderate to good yields. Moreover, sulfonamides were obtained after a simple oxidation reaction. The reaction mechanism was investigated by O-18-labeling experiments, and the synthetic utility was demonstrated by the sulfoxidation of natural products.