文献类型：期刊文献

中文题名：Pd(OAc)_(2)/PPh_(3)-Catalyzed Desulfonylative Homocoupling of Arylsulfonyl Chlorides

作者：Qiao Zhao[1];Liangshun Chen[1];Hongyue Lang[1];Shengying Wu[1];Limin Wang[1,2]

机构：[1]Shanghai Key Laboratory of Functional Materials Chemistry,East China University of Science and Technology,Shanghai 200237,China;[2]Key Laboratory of Organofluorine Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China

年份：2015

卷号：33

期号：5

起止页码：535

中文期刊名：Chinese Journal of Chemistry

外文期刊名：中国化学(英文版)

收录：CSTPCD;;Scopus;CSCD:【CSCD2015_2016】；PubMed;

基金：the National Natural Science Foundation of China(Nos.21272069,20672035);the Fundamental Research Funds for the Central Universities,and the Key Laboratory of Organofluorine Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences.

语种：英文

中文关键词：biaryls;arylsulfonyl chlorides;desulfonylative;palladium-catalyzed

摘要：The Pd-catalyzed homodimerization with respect to arylsulfonyl chlorides as an efficient method for the synthesisof biaryls has been developed.This desulfonylative reaction which was performed at reflux in 1,4-dioxane for 4h under air afforded the desired products in good to excellent yields.