文献类型：期刊文献

中文题名：Rh-Al-MCM-41上NO选择性催化还原的原位红外研究

英文题名：In situ IR Study on Selective Catalytic Reduction of Nitric Oxide by Propylene over Rh-AI-MCM-41

作者：万颖[1];王正[1];马建新[1];张益群[1];李建军[2]

机构：[1]华东理工大学工业催化研究所,上海200237;[2]上海石化催化剂研究所,200540

年份：2002

卷号：21

期号：3

起止页码：143

中文期刊名：上海环境科学

外文期刊名：Shanghai Environmental Sciences

收录：北大核心:【北大核心2000】；CSCD:【CSCD2011_2012】；CSSCI:【CSSCI2000_2002】；

基金：教育部重点科技项目(编号:93039);跨世纪优秀人才培养计划基金

语种：中文

中文关键词：Rh-Al-MCM-41;选择性催化还原;氮氧化物;原位红外;汽车;废气净化

外文关键词：Rh-Al-MCM-41 Elective catalytic reduction Nitric oxide In situ FTIR Purification of automobile exhaust gas

摘要：利用气-固相固定床反应装置考察了Rh交换的Al-MCM-41在高气体空速条件下对贫燃NOx的选择性催化还原活性,考察了氧含量对其的影响。结果表明,在200000h^(-1)的气体空速、O_2/C_3H_6=20、603K时,NO转化率为74.3％。利用原位FTIR技术研究了该催化剂的表面吸附物种及表面程序升温反应行为,并结合实验观察探讨了贫燃条件下Rh-Al-MCM-41催化剂上NO的选择性催化还原机理。
Rh-exchanged Al-MCM-41 has been studied for the selective catalytic reduction of NOX by C3H6 in the presence of excess oxygen. The results showed that over 74% conversion of NO was reached at 603K, and at O2 to C3H6 ratio of 10. Based on the observation of the adsorption species and reaction on the catalyst by in situ FTIR, a possible reaction pathway for reduction of NO by C3H6 was proposed. According to the mechanism, the activated propylene species will interact with Rh-NO2 to form organo-nitro species which reacts with O2 or NO2 to produce N2.