文献类型：期刊文献

英文题名：Highly diastereoselective synthesis of chiral aminophenolate zinc complexes and isoselective polymerization of rac-lactide

作者：Wang, Haobing;Ma, Haiyan[1]

机构：[1]E China Univ Sci & Technol, Shanghai Key Lab Funct Mat Chem, Shanghai 200237, Peoples R China; E China Univ Sci & Technol, Lab Organometall Chem, Shanghai 200237, Peoples R China

年份：2013

卷号：49

期号：77

起止页码：8686

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000323758900033)】；

基金：Financial support from the National Natural Science Foundation of China (NNSFC, 21074032) and the Fundamental Research Funds for the Central Universities (WK1214048, WD1113011) is gratefully acknowledged.

语种：英文

摘要：An enantiopure zinc complex supported by an aminophenolate ligand with multiple stereogenic centers has been diastereoselectively synthesized via the variation of the ortho-substituent of a phenoxy moiety and the N-alkyl group of a chiral pyrrolidinyl ring in the ligand framework, which displays high isoselectivity in the polymerization of rac-lactide.