文献类型：期刊文献

英文题名：Isobaric vapor-liquid equilibria of binary mixtures containing dimethyl carbonate under atmospheric pressure

作者：Luo, H.-P.[1]; Zhou, J.-H.[1]; Xiao, W.-D.[1]; Zhu, K.-H.[1]

机构：[1]E China Univ Sci & Technol, UNILAB Res Ctr Chem React Engn, Shanghai 200237, Peoples R China

年份：2001

卷号：46

期号：4

起止页码：842

外文期刊名：JOURNAL OF CHEMICAL AND ENGINEERING DATA

收录：;EI(收录号：2001356634348);WOS:【SCI-EXPANDED(收录号:WOS:000170043800012)】；

语种：英文

外文关键词：Atmospheric pressure - Gas chromatography - Mathematical models - Organic compounds - Phase equilibria - Statistical mechanics - Synthesis (chemical)

摘要：Isobaric vapor-liquid equilibria (VLE) have been determined for the binary systems of dimethyl carbonate (DMC) + ethanol, dimethyl carbonate + diethyl carbonate (DEC), dimethyl carbonate + propylene glycol (PG), and dimethyl carbonate + propylene carbonate (PC) under atmospheric pressure in an Ellis equilibrium still. The data have been checked by employing a global statistic thermodynamic consistency test and also have been correlated by means of both the Wilson equation and the NRTL equation. The experimental results demonstrated that the systems of DMC + ethanol and DMC + PG show strong positive deviations from ideality and that the systems of DMC + DEC and DMC + PC are close to ideality.