文献类型：期刊文献

中文题名：酸浓度对水解液中葡萄糖分解反应的影响研究

英文题名：INVESTIGATION OF THE EFFECT OF ACID CONCENTRATION ON THE DECOMPOSING REACTION OF GLUCOSE IN THE HYDROLYZATE

作者：亓伟[1];张素平[1];任铮伟[1];李庭琛[1];颜涌捷[1]

机构：[1]华东理工大学生物质能研究中心,上海200237

年份：2008

卷号：29

期号：11

起止页码：1395

中文期刊名：太阳能学报

外文期刊名：Acta Energiae Solaris Sinica

收录：CSTPCD;;EI(收录号：20085111797656);Scopus;北大核心:【北大核心2004】；CSCD:【CSCD2011_2012】；

基金：国家自然科学基金项目(50506010)

语种：中文

中文关键词：生物质;稀硫酸;葡萄糖;动力学

外文关键词：biomass; dilute sulfuric acid; glucose; kinetics

摘要：研究了酸氛下葡萄糖的分解特性,考察了酸浓度(0.05～0.20mol/L)、温度(150～200%)和反应时间(0～25min)对葡萄糖分解的影响。通过分析实验数据,运用数值计算方法对动力学参数进行估计,得到了该反应的表观活化能为136.83 kJ/mol,建立了能反映 H^+浓度对葡萄糖分解速率影响的动力学方程,其计算值与实验值的平均残差平方和为0.00382。
The decomposing properties were studied in the acid environment. The effects of acid concentration （from 0. 05mol/L to 0.2 mol/L）, reaction temperature （from 150℃ to 200℃ ） and reaction time （from 0 to 25min） on glucose decomposing were researched. The kinetic parameters were estimated by numerical calculation method and the activation energy of glucose decomposition reaction was obtained, which is 136.83 kJ/mol. The kinetic equation that can reflect the effect of hydrogen ion concentration on the rate constant of the decomposition reaction was established and the average quadratic sum of residual mean between calculating data and experimental data is about 0.00382.