文献类型：期刊文献

英文题名：Regulating carbonaceous mesophase structure by controlling nitrogen-containing aromatics of FCC slurry oil: Insights from MD simulations and experimental studies

作者：Wei, Xing-Guo[1];Zhang, Yuan-Qin[1];Cui, Ling-Rui[1];Liu, Cao[1];Huang, Jian[1];Cao, Fa-Hai[1]

机构：[1]East China Univ Sci & Technol, Sch Chem Engn, Shanghai 200237, Peoples R China

年份：2025

卷号：22

期号：7

起止页码：3015

外文期刊名：PETROLEUM SCIENCE

收录：;EI(收录号：20252718729259);WOS:【SCI-EXPANDED(收录号:WOS:001554105000001)】；

基金：The authors thank Research Center of Analysis and Test of East China University of Science and Technology for the help on the characterizations (elemental composition, S/N analyzer, group analysis, polarized light optical microscopy, XRD) . The authors extend their gratitude to Mr. Li Ning from Shiyanjia Lab ( www.shiyanjia.com ) for providing invaluable assistance with the TG, SEM, and Raman analysis. The authors thank Super Computing Network (SCNet, www.scnet.cn, AC.sugon.com ) for providing computational resources (Gaussian, Gromacs, and LAMMPS) . The authors acknowledge the support of National Natural Science Foundation of P. R. China (22308104) .

语种：英文

外文关键词：MD with ReaxFF; Pyrolysis behavior; Mesocarbon microbeads; Application of heavy oil; Nitrogen-containing aromatics; Morphology and structure

摘要：The influence of nitrogen-containing polycyclic aromatic hydrocarbons (NC-PAH) on the formation of carbonaceous mesophase remains enigmatic, despite extensive research on the production of carbonaceous materials from aromatic-rich oils. Molecular dynamics simulation was used to investigate the variations in pyrolysis behavior between PAH and NC-PAH based on the composition analysis. Through adjusting the content of NC-PAH, the influence of NC-PAH on the thermal stability of slurry oils (SOs) was evaluated by thermogravimetry, viscosity, coke value, and quinoline insoluble (QI). The morphology and structure of mesocarbon microbeads (MCMBs) prepared with SOs were measured by a polarized-light microscope, SEM, XRD, and Raman. Simulation results indicate that NC-PAH possesses much higher reactivity and tends to produce highly condensed solid and coke products. It corresponds to the QI and high viscosity in thermal stability experiments. Therefore, high concentrations of NC-PAH result in nonuniform morphology and disordered structures. In a system with low viscosity and few QIs, SO, which has a low nitrogen content (475 ppm), reacts gently to produce MCMBs with a uniform particle size (10-40 mm) and an excellent spherical shape. As NC-PAH content decreases, the crystalline size of graphitization elevates, as evidenced by parallel layers (10.472-11.764) and stack height (3.269 -3.701 nm). The graphitization degree becomes worse and nonuniform with the increase of the content of NC-PAH, and the best is 20.58% evaluated by Raman spectra area ratio (AG/Aall). Overall, this work suggests a nitrogen content reference and a controlling technology of nitrogen for the preparation of superior MCMB. (c) 2025 The Authors. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co. Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/ 4.0/).