文献类型：期刊文献

英文题名：Triphenylphosphine as a Ligand for the Pd-Catalyzed Amination of Unactivated Aryl Chlorides with Anilines Promoted by Salicylaldimine

作者：Liu, Tao-Ping[1];Cheng, Qiang[1];Song, Wen-Jing[1];Cai, Liang-Zhen[1];Tao, Xiao-Chun[1]

机构：[1]E China Univ Sci & Technol, Sch Chem & Engn, Shanghai 200237, Peoples R China

年份：2012

期号：16

起止页码：2333

外文期刊名：SYNLETT

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000309164100005)，CCR-EXPANDED(收录号:WOS:000309164100005)】；

基金：This work was supported by the Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials (Fudan University, 2012MCIMKF01). We thank Dr. Xiaomin Xie and Prof. Zhaoguo Zhang (Shanghai Jiao Tong University) for helpful discussions.

语种：英文

外文关键词：amination reaction; aryl chloride; salicylaldimine; diarylamine; triphenylphosphine

摘要：An efficient and selective amination of unactivated aryl chlorides with anilines catalyzed by mixed ligand Pd catalytic system of Ph3P-salicylaldimine has been developed for the preparation of diarylamines. The benzyne mechanism was ruled out based on experimental results.