文献类型：期刊文献

英文题名：The investigation of fluorination reaction of p-substituted benzenesulfonimides with fluorine-nitrogen mixed gas to synthesize NFSI analogues

作者：Chen, Guanlong[1,2];Chen, Fuli[1,2];Zhang, Yan[1,2];Yang, Xueyan[1,2];Yuan, Xiaoming[1,2];Wu, Fanhong[1,2,3];Yang, Xianjin[1,2,3,4]

机构：[1]E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China;[4]Wengfu Grp Co Ltd, Guizhou 550000, Peoples R China

年份：2012

卷号：133

起止页码：155

外文期刊名：JOURNAL OF FLUORINE CHEMISTRY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000300469500023)，CCR-EXPANDED(收录号:WOS:000300469500023)】；

基金：We thank the financial support of Guizhou Wengfu Group Company, Chinese Postdoctor Foundation, and New Teacher Foundation of Education Minister.

语种：英文

外文关键词：Benzenesulfonimide; Fluorination; NFSI analogue

摘要：This paper studied the fluorination reaction of p-substituted benzenesulfonimides with diluted elemental fluorine to synthesize N-fluoro-benzenesulfonimide (NFSI) analogues. Several synthetic methods were compared and we found that, for many p-substituted benzenesulfonimides, the fluorination of their sodium salts with 10% F-2-N-2 mixed gas in acetonitrile at room temperature could afford NFSI analogues in moderate to good yields. (C) 2011 Elsevier B.V. All rights reserved.