详细信息
文献类型:期刊文献
中文题名:用改进的形状因子法推算液体混合物的粘度
英文题名:Prediction of Viscosity for Liquid Mixtures by Improved Shape Factor Method
作者:刘辉[1];骆赞椿[1]
机构:[1]华东理工大学化学工程系
年份:1994
卷号:8
期号:3
起止页码:292
中文期刊名:高校化学工程学报
外文期刊名:Journal of Chemical Engineering of Chinese Universities
收录:CSTPCD;;Scopus;CSCD:【CSCD2011_2012】;
语种:中文
中文关键词:液体混和物;粘度;密度;形状因子
外文关键词:Viscosity, Density, Shape factor, Thermodynamics
摘要:本文对Ely的形状因子法引进编心因子修正,同时采用新的改进Rackett方程混合规则推算液体混合物密度。改进后的形状因子法在精度上有了显著的提高并能适用于极性系统。不同温度下26个二元系513个粘度数据及3个三元系36个粘度数据的预测结果,其绝对平均百分偏差(ADD)分别为3.11%和3.17%。
The acentric factor correction has been introduced to Ely's shape factor expresaion and a new mixing rule of modified Rackett equation has been used to calculate the density of liquid mixture. The remarkable improvement has been obtained by using the modified Ely's method which is applicable to polar compounds and low carbon number alcohol systems. o13 data points of viscosity for 26 binary systems and 36 points for 3 ternary systems have been predicted by the suggested method,the AAD are 3. 11% and 3. 17% respectively.
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