文献类型：期刊文献

英文题名：Development and outlook of chiral carbene-gold(I) complexes catalyzed asymmetric reactions

作者：Gu, Peng[1,2];Xu, Qin[1,2];Shi, Min[1,2,3]

机构：[1]E China Univ Sci & Technol, Sch Chem & Mol Engn, Key Lab Adv Mat, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Sch Chem & Mol Engn, Inst Fine Chem, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

年份：2014

卷号：55

期号：3

起止页码：577

外文期刊名：TETRAHEDRON LETTERS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000330153000001)】；

基金：We thank the Shanghai Municipal Committee of Science and Technology (11JC1402600), the National Basic Research Program of China (973)-2010CB833302, the Fundamental Research Funds for the Central Universities, and the National Natural Science Foundation of China for financial support (21072206, 20472096, 20872162, 20672127, 21102166, 21121062 and 20732008).

语种：英文

外文关键词：Chiral carbene-gold(I) complexes; Asymmetric reactions; N-Heterocyclic carbene ligands; Nitrogen acyclic carbene ligands; Hydrogen bonded heterocyclic carbene ligands

摘要：Great progress has been made in developing of homogeneous Au-catalyzed reactions in the past decade. The unique versatility and efficiency of gold complexes have been obtained including carbene ligated gold complexes. Due to the special linear coordination mode of gold(I) complex, Au catalyzed asymmetric reactions have become a huge challenge. Chiral carbene-gold complexes also have been applied in asymmetric reactions. Major breakthrough in this field has been obtained by the Toste group recently and more are expected in the future. This digest, by highlighting recent works, aims to make further progress in this fascinating research field. (C) 2013 Elsevier Ltd. All rights reserved.