文献类型：期刊文献

英文题名：Synthesis, structures, and catalytic reactions of ring-substituted titanium(IV) complexes

作者：Qian, Yanlong[1]; Huang, Jiling[1]; Bala, Muhammad D.[1]; Lian, Bing[1]; Zhang, Hao[1]; Zhang, Hao[1]

机构：[1]E China Univ Sci & Technol, Organ Chem Lab, Shanghai 200237, Peoples R China

年份：2003

卷号：103

期号：7

起止页码：2633

外文期刊名：CHEMICAL REVIEWS

收录：;EI(收录号：2003327586201);WOS:【SCI-EXPANDED(收录号:WOS:000184244100006)】；

语种：英文

外文关键词：Catalysis - Complexation - Monomers - Polymerization - Substitution reactions - Synthesis (chemical)

摘要：A study was performed on the synthesis, structures and catalytic reactions of ring-substituted titanium(IV) complexes. The synthetic methodologies to various classes of titanocenes based on the nature of ring substitution were reviewed. It was shown that the half-sandwich titanocenes and the constrained geometry linked-amido cyclopentadienyl(indenyl) titanium complexes remain the most active area of titanium research.