文献类型：期刊文献

英文题名：An Efficient Biomimetic Aerobic Oxidation of Alcohols Catalyzed by Iron Combined with Amino Acids

作者：Zhang, Guofu[1];Li, Shasha[1];Lei, Jie[1];Zhang, Guihua[1];Xie, Xiaoqiang[1];Ding, Chengrong[1];Liu, Renhua[2]

机构：[1]Zhejiang Univ Technol, Coll Chem Engn, 18 Chaowang Rd, Hangzhou 310014, Zhejiang, Peoples R China;[2]E China Univ Sci & Technol, Sch Pharm, 130 Meilong Rd, Shanghai 200237, Peoples R China

年份：2016

卷号：27

期号：6

起止页码：956

外文期刊名：SYNLETT

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000372984600029)，CCR-EXPANDED(收录号:WOS:000372984600029)】；

基金：We acknowledge financial support from the National Natural Science Foundation of China ( no. 20702051), the Natural Science Foundation of Zhejiang Province (LY13B020017) and the Key Innovation Team of Science and Technology in Zhejiang Province ( no. 2010R50018).

语种：英文

外文关键词：alcohols; aldehydes; amino acids; iron; ketones; oxidation

摘要：A novel combination of FeCl3, l-valine and TEMPO is found to oxidize alcohols to the carbonyl compounds with dioxygen. A wide range of primary/secondary benzyl, allylic, and heterocyclic alcohols have been efficiently converted into aldehydes and ketones with good to excellent isolated yields.