文献类型：期刊文献

英文题名：WO₃/TiO₂ composite with morphology change via hydrothermal template-free route as an efficient visible light photocatalyst

作者：Leghari, Sajjad Ahmed Khan;Sajjad, Shamaila;Chen, Feng;Zhang, Jinlong[1]

机构：[1]E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China; E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China

年份：2011

卷号：166

期号：3

起止页码：906

外文期刊名：CHEMICAL ENGINEERING JOURNAL

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000287901900013)】；

基金：This work has been supported by National Nature Science Foundation of China (20773039 and 20977030), National Basic Research Program of China (973 Program, 2007CB613301 and 2010CB732306), Science and Technology Commission of Shanghai Municipality (10520709900 and 10JC1403900) and the Fundamental Research Funds for the Central Universities. Sajjad Ahmed Khan Leghari and Shamaila Sajjad thank Higher Education Commission (Pak.) for support.

语种：英文

外文关键词：Template-free route; Hydrothermal method; WO3/TiO2 composite; Ammonium sulfate; Visible photocatalyst

摘要：The WO3/TiO2 composites are prepared by a template-free synthetic approach based on hydrothermal reaction that leads to the formation of nanoparticles and microspheres with the change in concentrations of ammonium tungstate used as a dopant precursor. 5.0% composite generally exists in loose aggregate nanoparticles. These particles are aggregated to form the peculiar morphology of microspheres at 10.0% WO3/TiO2 due to the in situ formation of ammonium sulfate in supersaturated state. 5.0% composite exhibits the best photoactivity as compared to pure TiO2, P-25 and pure WO3 in the degradation of methyl orange and 2, 4-dichlorophenol in UV and visible light. 10.0% WO3/TiO2 composite contains more dopant contents but exhibits comparable higher activity due to its specific morphology of spheres. Morphological variations of a photocatalyst also influence the photocatalytic efficiencies. Catalysts exhibit high activity owing to the combined effects of both the unique structural characteristics and the tungsten doping. The doped tungsten (W) inhibits the electron-hole recombination rate. The kinetics of the organics degradation is found to follow the Langmuir-Hinshelwood model. (C) 2010 Elsevier B.V. All rights reserved.