文献类型：期刊文献

英文题名：Highly Enantioselective Epoxidation of α,β-Unsaturated Ketones Catalyzed by Primary-Secondary Diamines

作者：Lu, Yingpeng[1,2,3];Zheng, Changwu[1];Yang, Yingquan[1];Zhao, Gang[1];Zou, Gang[2,3]

机构：[1]Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Synthet Chem Nat Subst, Shanghai 200032, Peoples R China;[2]E China Univ Sci & Technol, Adv Mat Lab, Shanghai 200237, Peoples R China;[3]E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China

年份：2011

卷号：353

期号：17

起止页码：3129

外文期刊名：ADVANCED SYNTHESIS & CATALYSIS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000298171500009)，CCR-EXPANDED(收录号:WOS:000298171500009)】；

基金：Research support from National Basic Research Program of China (973 Program, 2010CB833300), the National Natural Science Foundation of China (No. 20172064, 203900502, 21032006), Shanghai Natural Science Council, and Excellent Young Scholars Foundation of National Natural Science Foundation of China (20525208) is gratefully acknowledged.

语种：英文

外文关键词：asymmetric catalysis; cumene hydroperoxide; enones; epoxidation; organocatalysis

摘要：The asymmetric epoxidation of alpha,beta-unsaturated ketones has been achieved by using functional and readily accessible primary-secondary diamines as the catalysts, giving the useful alkyl epoxy products with good yields and high enantioselectivities (up to 99% ee).