文献类型：会议论文

英文题名：Unusual adsorption and desorption behaviors of NO and CO on nanoporous nickel phosphate VSB-5: In situ FT-IR and TPD study

作者：Chen, Zhi[1,2];Zhou, Dantong[1];Gao, Tong[1];Shen, Weihua[3];Dong, Xiaoping[4];Naito, Shuichi[2];Qin, Laishun[1];Huang, Yuexiang[1]

机构：[1]China Jiliang Univ, Coll Mat Sci & Engn, Hangzhou 310018, Zhejiang, Peoples R China;[2]Kanagawa Univ, Dept Mat & Life Chem, Kanagawa Ku, Yokohama, Kanagawa 2218686, Japan;[3]E China Univ Sci & Technol, Sch Chem Engn, Shanghai 200237, Peoples R China;[4]Zhejiang Sci Tech Univ, Sch Sci, Dept Chem, Hangzhou 310018, Zhejiang, Peoples R China

会议论文集：1st International Symposium on Catalytic Science and Technology in Sustainable Energy and Environment (EECAT)

会议日期：OCT 08-10, 2014

会议地点：Tianjin, PEOPLES R CHINA

语种：英文

外文关键词：Nanoporous nickel phosphate VSB-5; NO adsorption/desorption; CO adsorption/desorption; Isotopic labeled adsorption; In situ FTIR; TPD

摘要：To develop new catalyst for controlling NO emission is important for pollution control. The investigation of NO or CO adsorption could contribute the fundamental understanding the reaction mechanism of de-NOx process and the coordinate state of the specific catalyst. Nanoporous nickel phosphate VSB-5 is an attractive catalyst and is firstly employed as the active component for the adsorption of NO and/or CO. In situ FT-IR and temperature programmed desorption (TPD) are used to characterize the adsorption behaviors. A large amount of NO and/or CO can be adsorbed in the pores of VSB-5 and strong bands from different adsorbed species are observed by in situ FT-IR investigation, which is confirmed by isotopic labeled adsorption. The amount of adsorption at room temperature unusually increases by raising the adsorption temperature to 100-200 degrees C. The possible reason may be explained by the generation of more active sites at elevated temperature which plays a more important role than corresponding desorption. The adsorption of CO and NO is competitive and the adsorbed CO may be replaced by NO due to a stronger bonding strength of the latter. This report contributes to monitor the active sites in the pores of VSB-5 and also makes VSB-5 to be an active candidate for NO or CO related catalytic process. (C) 2015 Elsevier B.V. All rights reserved.