文献类型：期刊文献

英文题名：INTERNAL-PRESSURE AND SOLUTION THEORY FOR NONELECTROLYTES

作者：LIU, GJ; SHI, JB; HEI, EC

年份：1994

卷号：52

期号：4

起止页码：352

外文期刊名：ACTA CHIMICA SINICA

收录：;WOS:【SCI-EXPANDED(收录号:WOS:A1994NU70200008)】；

语种：英文

摘要：A theory of nonathermal solutions for nonelectrolytes has been established by a thermodynamic method. This theory does not contain any adjustable parameters. The excess Gibbs free energy of liquid mixtures can be predicted by properties of pure components which are related to their internal pressure. The excess enthalpy and entropy can also be calculated, if the volume of liquid mixture is known. The results of prediction show that the agreement with experimental values prevails over that by the Scatchard-Hildebrand theory of regular solutions and its modified version, SHFH theory for most of thirty-seven binary systems.