文献类型：期刊文献

英文题名：Preparation of Nitrogen-Doped Graphene Sheets by a Combined Chemical and Hydrothermal Reduction of Graphene Oxide

作者：Long, Donghui[1,2];Li, Wei[1];Ling, Licheng[2];Miyawaki, Jin[1];Mochida, Isao[1];Yoon, Seong-Ho[1]

机构：[1]Kyushu Univ, Inst Mat Chem & Engn, Fukuoka 8168580, Japan;[2]E China Univ Sci & Technol, State Key Lab Chem Engn, Shanghai 200237, Peoples R China

年份：2010

卷号：26

期号：20

起止页码：16096

外文期刊名：LANGMUIR

收录：;EI(收录号：20104213304040);WOS:【SCI-EXPANDED(收录号:WOS:000282936700054)】；

语种：英文

外文关键词：Doping (additives) - Nitrogen compounds - Electrolytic reduction - Hydrothermal synthesis - Nitrogen - Graphene oxide

摘要：Nitrogen-doped graphene sheets were prepared through a hydrothermal reduction of colloidal dispersions of graphite oxide in the presence of hydrazine and ammonia at of 10. The effect of hydrothermal temperature on the structure, morphology, and surface chemistry of as-prepared graphene sheets were investigated though XRD, N-2 adsorption, solid-state C-13 NMR, SEM, TEM, and XPS characterizations. Oxygen reduction and nitrogen doping were achieved simultaneously under the hydrothermal reaction. Up to 5% nitrogen-doped graphene sheets with slightly wrinkled and folded feature were obtained at the relative low hydrothermal temperature. With the increase of hydrothermal temperature, the nitrogen content decreased slightly and more pyridinic N incorporated into the graphene network. Meanwhile, a jellyfish-like graphene structure was formed by self-organization of graphene sheets at the hydrothermal temperature of 160 degrees C. Further increase of the temperature to 200 degrees C, graphene sheets could self-aggregate into agglomerate particles but still contained doping level of 4 wt % N. The unique hydrothermal environment should play an important role in the nitrogen doping and the jellyfish-like graphene formation. This simple hydrothermal method could provide the synthesis of nitrogen-doped graphene sheets in large scale for various practical applications.