文献类型：期刊文献

英文题名：Pyrrolylmethylene Appended Corrorin: Peripheral Coordination and Transformation to Pyridyl Incorporated Hemiporphycene Analogue

作者：Xu, Yue[1];Zhu, Bin[1];Li, Qizhao[1];Sha, Feng[1];Baryshnikov, Glib[2];He, Lanka[1];Feng, Yifan[1];Tang, Jingxuan[1];Wei, Yuan[1];Li, Chengjie[1];Wu, Xinyan[1];agren, Hans[3];Xie, Yongshu[1]

机构：[1]East China Univ Sci & Technol, Inst Fine Chem, Frontiers Sci Ctr Materiobiol & Dynam Chem, Sch Chem & Mol Engn,Key Lab Adv Mat, Shanghai 200237, Peoples R China;[2]Linkoping Univ, Dept Sci & Technol, Lab Organ Elect, SE-60174 Norrkoping, Sweden;[3]Uppsala Univ, Dept Phys & Astron, SE-75120 Uppsala, Sweden

年份：2023

卷号：25

期号：10

起止页码：1793

外文期刊名：ORGANIC LETTERS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000946486100001)】；

基金：This research at ECUST was financially supported by NSFC (22131005, 21971063, 22201074, and 22075077) , Program of Introducing Talents of Discipline to Universities (B16017) , the Fundamental Research Funds for the Central Universities (222201717003) , Program of Shanghai Academic Research Leader (20XD1401400) , and Natural Science Foundation of Shanghai (22ZR1416100, 20ZR1414100) . G.B. thanks the Swedish National Infrastructure for Computing (SNIC) resources at the High -Performance Computing Center North (HPC2N) and the Swedish Research Council financial support (2018-05973, 2020-04600) . The authors thank the Research Center of Analysis and Test of East China University of Science and Technology for the help on the characterization.

语种：英文

摘要：A pyrrolylmethylene appended corrorin 1 was synthesized and coordinated with [Rh(CO)2Cl]2 to afford 1-Rh with unique RhI-eta 2-CC bonding in addition to the coordination of the dipyrrin-like unit and a carbonyl ligand. Further oxidation of 1 afforded 2, exhibiting a hydrocorrorinone core, and it can be further transformed into pyrrolo[3,2c]pyridine incorporated hemiporphycene analogue 3 upon treatment with HOAc. The side chain modifies the reactivity of corrorin and effectively tunes the NIR absorption of the resulting porphyrinoids.