文献类型：期刊文献

英文题名：Synthesis and spectroscopic and electrochemical properties of TTF-derivatized polycarbazole

作者：Liu, Yibo[1,2];Wang, Chengyun[1,2];Li, Meiffiang[3];Lai, Guoqiao[3];Shen, Yongjia[1,2]

机构：[1]E China Univ Sci & Technol, Adv Mat Lab, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China;[3]Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 310012, Peoples R China

年份：2008

卷号：41

期号：6

起止页码：2045

外文期刊名：MACROMOLECULES

收录：;EI(收录号：20081511199760);WOS:【SCI-EXPANDED(收录号:WOS:000254133200023)】；

语种：英文

外文关键词：Catalyst activity - Coupling agents - Cyclic voltammetry - Polymers - Reaction kinetics

摘要：Two polycarbazoles with tetrathiafulvalene (TTF) as pendant group were synthesized first by Yamamoto coupling reaction using Ni(1,5-cyclooctadiene)(2) (Ni(COD)(2)) as the catalyst. The structures of the polymers and their intermediates were characterized by H-1 NMR, C-13 NMR, MS, GPC, UV-vis, and IR. The electrochemical behaviors of the polymers were characterized by cyclic voltarnmetry. These polymers exhibit higher conductivity up to about 0.1 S cm(-1).