文献类型：期刊文献

中文题名：Light-driven interconversion of Pd_(2)L_(4)cage and mononuclear PdL_(2)mediated by the isomerization of azobenzene ligand

作者：Jinkang Zhu[1];Xujin Chen[1];Xin Jin[1];Qiaochun Wang[1]

机构：[1]Key Laboratory for Advanced Materials,Joint International Research Laboratory of Precision Chemistry and Molecular Engineering,Feringa Nobel Prize Scientist Joint Research Center,Frontiers Science Center for Materiobiology and Dynamic Chemistry,Institute of Fine Chemicals,School of Chemistry and Molecular Engineering,East China University of Science and Technology,Shanghai 200237,China

年份：2023

卷号：34

期号：6

起止页码：358

中文期刊名：Chinese Chemical Letters

外文期刊名：中国化学快报（英文版）

收录：CSTPCD;;Scopus;CSCD:【CSCD2023_2024】；PubMed;

基金：financially supported by the National Natural Science Foundation of China(No.21572063);Shanghai Municipal Science and Technology Major Project(No.2018SHZDZX03);the Fundamental Research Funds for the Central Universities。

语种：英文

中文关键词：Molecular cage;Azobenzene;Isomerization;Pd_(2)L_(4);PdL_(2)

摘要：The lantern-shaped cage Pd_(2)L_(4)and tweezer-like PdL_(2)can be synthesized from the trans-and cis-isomer of an azobenzene-containing ligand,respectively,which were characterized by^(1)H,^(13)C,^(1)H-^(1)H COSY,DOSY NMR spectroscopies,high-resolution ESI-MS and density function theory(DFT)calculations.The interconversion of Pd_(2)L_(4)and PdL_(2)can be achieved via the cis-trans isomerization of the azobenzene unit on the ligand upon alternative irradiation of light 365 nm or 420 nm.