文献类型：期刊文献

中文题名：Axially Chiral C2-Symmetric N-Heterocyclic Carbene （NHC） Palladium Complex-Catalyzed Asymmetric Fluorination and Amination of Oxindoles

英文题名：Axially Chiral C2-Symmetric N-Heterocyclic Carbene (NHC) Palladium Complex-Catalyzed Asymmetric Fluorination and Amination of Oxindoles

作者：Zhang Rui[1,2];Wang De[1,2];Xu Qin[1,2];Jiang Jiajun[1,2];Shi Min[1,2,3]

机构：[1]E China Univ Sci & Technol, Sch Chem & Mol Engn, Key Lab Adv Mat, Shanghai 200237, Peoples R China;[2]E China Univ Sci & Technol, Sch Chem & Mol Engn, Inst Fine Chem, Shanghai 200237, Peoples R China;[3]Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

年份：2012

卷号：30

期号：6

起止页码：1295

中文期刊名：Chinese Journal of Chemistry

外文期刊名：CHINESE JOURNAL OF CHEMISTRY

收录：;Scopus;WOS:【SCI-EXPANDED(收录号:WOS:000305389200018)，CCR-EXPANDED(收录号:WOS:000305389200018)】；CSCD:【CSCD2011_2012】；

基金：We thank the Shanghai Municipal Committee of Science and Technology (No. 11JC1402600), National Basic Research Program of China [No. (973)-2010CB833302], the Fundamental Research Funds for the Central Universities and the National Natural Science Foundation of China for financial support (Nos. 21072206, 20872162, 20672127, 20732008, 21121062 and 20702013).

语种：英文

中文关键词：chiral C2-symmetric N-heterocyclic carbene （NHC） palladium diaquo complex;（S）-B1NAM;asym-metric fluorination of oxindoles;N-fluorobenzenesulfonimide （NFSI）;1-chloromethyl-4-fluoro-l,4-diazoniabi-cyclo[2.2.2]octane bis（tetrafluoroborate） （selectfluor）

外文关键词：chiral C2-symmetric N-heterocyclic carbene (NHC) palladium diaquo complex; (S)-BINAM; asymmetric fluorination of oxindoles; N-fluorobenzenesulfonimide (NFSI); 1-chloromethyl-4-fluoro-1; 4-diazoniabicyclo[2; 2; 2]octane bis(tetrafluoroborate) (selectfluor)

摘要：Chiral C2-symmetric N-heterocyclic carbene （NHC） palladium diaquo complex 5b prepared from （S）-BINAM was found to be a fairly effective catalyst for the enantioselective asymmetric fluorination of oxindoles to give the corresponding products in moderate enantioselectivities along with good to excellent yields.
Chiral C2-symmetric N-heterocyclic carbene (NHC) palladium diaquo complex 5b prepared from (S)-BINAM was found to be a fairly effective catalyst for the enantioselective asymmetric fluorination of oxindoles to give the corresponding products in moderate enantioselectivities along with good to excellent yields.