文献类型：期刊文献

英文题名：Diaryliodonium Salts Enabled Arylation, Arylocyclization, and Aryl-Migration

作者：Pan, Cheng[1,2,3];Wang, Limin[1,2,3];Han, Jianwei[1,2,3]

机构：[1]East China Univ Sci & Technol, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China;[2]East China Univ Sci & Technol, Dept Fine Chem, 130 Meilong Rd, Shanghai 200237, Peoples R China;[3]East China Univ Sci & Technol, Inst Fine Chem, Sch Chem & Mol Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China

年份：2023

卷号：23

期号：10

外文期刊名：CHEMICAL RECORD

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000997098400001)】；

基金：Acknowledgments The work was supported by the Natural Science Foundation of Shanghai (20ZR1413500). The authors thank Research Center of Analysis and Test of East China University of Science and Technology for the help on the characterization.

语种：英文

外文关键词：diaryliodonium salts; synthetic methodology; arylation; arylocyclization; benzocyclization

摘要：Our research interest focusing on synthetic methodology with diaryliodonium salts, is summarized in this account. Besides employing a dual activation strategy of C-I and ortho C-H bonds, we have introduced vicinal functional groups at ortho-positions of diaryliodonium salts, in which their unique reactivities have been explored in various processes, including arylation, diarylation, cascade annulation, benzocyclization, arylocyclization, and intramolecular aryl migration. The variety of mechanisms of these reactions that involves either transition metals, especially palladium in organometallic catalysis, or transition-metal free conditions, were discussed in the context.