文献类型：期刊文献

英文题名：Palladium-catalyzed asymmetric 1,6-addition of diphenylphosphine to (4-aryl-1,3-butadienylidene)bis(phosphonates) for the synthesis of chiral phosphines

作者：Huang, Jian[2];Zhao, Mei-Xin[2];Duan, Wei-Liang[1]

机构：[1]Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China;[2]E China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China

年份：2014

卷号：55

期号：3

起止页码：629

外文期刊名：TETRAHEDRON LETTERS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000330153000011)，CCR-EXPANDED(收录号:WOS:000330153000011)】；

基金：The National Basic Research Program of China (973 Program 2010CB833300), NSFC (20902099, 21172238), and SIOC are greatly acknowledged for funding this work.

语种：英文

外文关键词：Asymmetric 1,6-addition; Pincer palladium catalyst; Chiral phosphines; Bis(phosphonate)-substituted dienes

摘要：An asymmetric 1,6-addition of diphenylphosphine to (4-aryl-1,3-butadienylidene)bis(phosphonates) catalyzed by a PCP pincer-Pd complex has been developed for the synthesis of chiral allylic phosphines with up to 91% ee under mild conditions. (C) 2013 Elsevier Ltd. All rights reserved.