文献类型：期刊文献

英文题名：Iron Chloride/4-Acetamido-TEMPO/Sodium Nitrite-Catalyzed Aerobic Oxidation of Primary Alcohols to the Aldehydes

作者：Yin, Weili[1];Chu, Changhu[1];Lu, Qiongqiong[1];Tao, Jianwei[1];Liang, Xinmiao[1,2];Liu, Renhua[1]

机构：[1]E China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China;[2]Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

年份：2010

卷号：352

期号：1

起止页码：113

外文期刊名：ADVANCED SYNTHESIS & CATALYSIS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000274339500009)，CCR-EXPANDED(收录号:WOS:000274339500009)】；

基金：This work was supported by grants from the National High Technology Research and Development Program of China (863 Program) (No. 2008AA06Z306) and the National Natural Science Foundation of China (No. 20572110).

语种：英文

外文关键词：aerobic oxidation; iron chloride; primary alcohols; sodium nitrite; TEMPO

摘要：A variety of 4-substituted 2,2,6,6-tetramethylpiperidyl-1-oxy (TEMPO) derivatives has been screened for their ability in the oxidation of primary alcohols to the aldehydes with dioxygen under mild conditions. An evaluation of the efficiency of these 4-substituted TEMPO derivatives in the alcohol oxidation may allow an insight into the effect of the structural variations of TEMPO on the oxidation of alcohols, which should facilitate catalyst design and screening efforts. Based on the screening results of 4-substituted TEMPO derivatives, the catalyst comprised of 4-acetamido-TEMPO, iron chloride and sodium nitrite, has been developed for the highly efficient oxidation of a wide range of primary alcohols including primary aliphatic alcohols to the corresponding aldehydes under mild conditions.