文献类型：期刊文献

英文题名：Mass Transport and Electron Transfer at the Electrochemical- Confined Interface

作者：Lu, Si -Min[1,2];Chen, Jian-Fu[1];Wang, Hai-Feng[1];Hu, Peijun[1,3];Long, Yi-Tao[2]

机构：[1]East China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China;[2]Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Analyt Chem Life Sci, Nanjing 210023, Peoples R China;[3]Queens Univ Belfast, Sch Chem & Chem Engn, Belfast BT95AG, North Ireland

年份：2023

卷号：14

期号：5

起止页码：1113

外文期刊名：JOURNAL OF PHYSICAL CHEMISTRY LETTERS

收录：;EI(收录号：20230513536404);WOS:【SCI-EXPANDED(收录号:WOS:000929751100001)】；

基金：? ACKNOWLEDGMENTS This research was supported by National Key R&D Program of China (2021YFA1500700) , the National Natural Science Foundation of China (21703067, 92045303, and 22206074) , and the Fundamental Research Funds for the Central Universities (2022300325) .

语种：英文

外文关键词：Electron transitions - Stochastic systems

摘要：Single entity measurements based on the stochastic collision electrochemistry provide a promising and versatile means to study single molecules, single particles, single droplets, etc. Conceptually, mass transport and electron transfer are the two main processes at the electrochemically confined interface that underpin the most transient electrochemical responses resulting from the stochastic and discrete behaviors of single entities at the microscopic scale. This perspective demonstrates how to achieve controllable stochastic collision electrochemistry by effectively altering the two processes. Future challenges and opportunities for stochastic collision electrochemistry are also highlighted.