文献类型：期刊文献

英文题名：Transforming bulk alkenes and alkynes into fine chemicals enabled by single-atom site catalysis

作者：Guo, Ping[1];Liu, Hongyuan[1];Zhao, Jie[1,2]

机构：[1]East China Univ Sci & Technol, Key Lab ForAdv Mat & Joint Int Res Lab Precis Che, Feringa Nobel Prize Scientist Joint Res Ctr, Sch Chem & Mol Engn,Frontiers Sci Ctr Materiobiol, Shanghai 200237, Peoples R China;[2]Tsinghua Univ, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Minist Educ, Dept Chem, Beijing 100084, Peoples R China

年份：2022

卷号：15

期号：9

起止页码：7840

外文期刊名：NANO RESEARCH

收录：;EI(收录号：20222712305665);WOS:【SCI-EXPANDED(收录号:WOS:000817845100002)】；

基金：J. Z. acknowledges Project supported by Shanghai Municipal Science and Technology Major Project (No. 2018SHZDZX03) and the Program of Introducing Talents of Discipline to Universities (No. B16017).

语种：英文

外文关键词：single-atom site catalysts (SACs); alkenes; alkynes

摘要：The addition and substitution reactions across a variety of alkenes and alkynes have been playing an important role in organic synthesis. In particular, catalyses enabled by homogeneous complexes as well as heterogenous nanomaterials have been much received attentions over decades. Along with these blooming progresses in these fields, single-atom site catalysts (SACs) exhibit outstanding performances in terms of reactivity and selectivity, thus providing a new powerful strategy to upgrade these bulk chemicals. Herein, we summarize the reactions of alkenes and alkynes enabled by SACs, in which catalytic hydrogenation, hydrosilylation, hydroboration, hydroformylation, and cross coupling have been included. Moreover, preparations and fine structures of the corresponding SACs have been described, therefore providing a better understanding and overview to address the origin of catalytic activity in the reported examples.