文献类型：期刊文献

英文题名：Facile one-pot synthesis of a nitrogen-doped mesoporous carbon architecture with cobalt oxides encapsulated in graphitic layers as a robust bicatalyst for oxygen reduction and evolution reactions

作者：Hu, Wenhui[1];Wang, Qing[1];Wu, Shanshan[1];Huang, Yongmin[1]

机构：[1]East China Univ Sci & Technol, Key Lab Specially Funct Polymer Mat & Related Tec, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China

年份：2016

卷号：4

期号：43

起止页码：16920

外文期刊名：JOURNAL OF MATERIALS CHEMISTRY A

收录：;EI(收录号：20164503000097);WOS:【SCI-EXPANDED(收录号:WOS:000387878700020)】；

基金：This work was supported by the National Natural Science Foundation of China (No. 21476071) and Shanghai Leading Academic Discipline Project (B502).

语种：英文

外文关键词：Iridium compounds - Electrolytic reduction - Energy conversion - Platinum compounds - Synthesis (chemical) - Doping (additives) - Electrodes - Oxygen - Cobalt compounds - Nitrogen

摘要：The development of future energy technology relies deeply on the design of cheap, sustainable and efficient systems for energy conversion and storage. As for the widespread oxygen electrode reactions, exploiting high efficiency and stable catalysts to boost both oxygen reduction (ORR) and evolution reactions (OER) seems to be a paramount mission. Here, we report a nitrogen-doped mesoporous carbon material with cobalt oxide nanoparticles encapsulated in the graphitic layers via a facile one-pot synthesis. Strikingly, the as-fabricated Co-N/C 800 affords a low reversible overvoltage of 0.96 V between ORR and OER, surpassing 270, 390 and 460 mV in potential over 20 wt% Pt/C, RuO2 and IrO2, which makes it a high performance non-precious metal bicatalyst for reversible oxygen electrode reactions.