文献类型：期刊文献

英文题名：Aminocatalyzed asymmetric Diels-Alder reaction of 2,4-dienals and rhodanine/hydantoin derivatives

作者：Zhu, Kailong[1];Huang, Huicai[1];Wu, Wenbin[1];Wei, Yuan[1];Ye, Jinxing[1]

机构：[1]E China Univ Sci & Technol, Minist Educ, Sch Pharm, Engn Res Ctr Pharmaceut Proc Chem, Shanghai 200237, Peoples R China

年份：2013

卷号：49

期号：21

起止页码：2157

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000314893200020)，CCR-EXPANDED(收录号:WOS:000314893200020)】；

基金：We thank the National Natural Science Foundation of China (20902018, 21272068), Shanghai Municipal Education Commission (11ZZ56), the Fundamental Research Funds for the Central Universities, and 111 project (B07023) for financial support.

语种：英文

摘要：Aminocatalyzed asymmetric Diels-Alder reaction between 2,4-dienals and rhodanine/hydantoin derivatives via trienamine mechanism has been developed to synthesize various spirocyclic compounds with good yields (up to 98%) and excellent stereoselectivities (up to 99% ee and >19 : 1 dr).