文献类型：期刊文献

中文题名：催化湿式共氧化法同时去除硝基苯和苯酚（英文）

英文题名：Simultaneous removal of nitrobenzene and phenol by homogenous catalytic wet air oxidation

作者：付冬梅[1];章飞芳[2];王联芝[3];杨帆[1];梁鑫淼[1]

机构：[1]中国科学院大连化学物理研究所,辽宁大连116023;[2]华东理工大学药学院,上海200237;[3]湖北民族学院化学与环境工程学院,湖北恩施445000

年份：2015

卷号：36

期号：7

起止页码：952

中文期刊名：催化学报

外文期刊名：CHINESE JOURNAL OF CATALYSIS

收录：CSTPCD;;EI(收录号：20152600982673);Scopus;WOS:【SCI-EXPANDED(收录号:WOS:000356911400005)】；北大核心:【北大核心2014】；CSCD:【CSCD2015_2016】；

基金：This work was supported by the National Natural Science Foundation of China (21107108 and 21267009) and the Key Project of Knowledge Innovation Program of the Chinese Academy of Sciences (KJCX2-YW-H04).

语种：中文

中文关键词：催化湿式氧化;共氧化;均相催化剂;高级氧化技术;废水处理

外文关键词：Catalytic wet air oxidation Co-oxidation Homogenous catalyst Advanced oxidation processWastewater treatment

摘要：在150–210 oC,1.0 MPa氧分压条件下,对催化湿式共氧化法同时去除硝基苯和苯酚进行了研究.与无催化剂共氧化降解苯酚和硝基苯相比,均相催化剂的加入极大提高了苯酚和硝基苯的去除.在所研究的过渡金属催化剂中,Cu2+,Co2+和Ni2+是有效的催化剂,其中Cu2+的催化活性最好.引发剂苯酚的连续加入模式对硝基苯的去除有很大的促进作用,分批加入苯酚的促进作用更明显.在200 oC,以Cu2+为催化剂,苯酚分两次加入,反应1 h,硝基苯去除率达到95%.这种催化共氧化体系以及分批进样引发剂的反应模式对有效去除环境中其它有机污染物提供了一种方法.
The simultaneous wet air oxidation of nitrobenzene （NB） and phenol with homogenous catalyst was carried out in a stainless autoclave in a temperature range of 150-210℃ and at a partial oxygen pressure of 1.0 MPa. Compared with the non-catalytic co-oxidation of NB and phenol, the presence of the homogeneous catalyst greatly improved the conversion of both compounds. The transition metal ions Cu2＋, Co2. and Ni2＋ were found to be effective catalysts, with Cu2. affording the best resuits. How phenol was added to the autoclave was investigated and was found to affect the conversion of NB. Adding phenol in smaller portions can help to degrade NB more effectively. As an exam- ple, two additions of phenol with Cu2＋ as the homogenous catalyst allowed 95% conversion of NB at 200℃ in 1 h. This catalytic co-oxidation method incorporating the addition of phenol initiator batches therefore provides an alternative and effective means of removing persistent organic pollutants from the environment.