文献类型：期刊文献

英文题名：Palladium-catalyzed hydroformylation of terminal arylacetylenes with glyoxylic acid

作者：Liu, Yang[1];Cai, Liangzhen[1];Xu, Sheng[1];Pu, Weiwen[1];Tao, Xiaochun[1]

机构：[1]East China Univ Sci & Technol, Sch Chem & Mol Engn, 130 Mei Long Rd, Shanghai 200237, Peoples R China

年份：2018

卷号：54

期号：17

起止页码：2166

外文期刊名：CHEMICAL COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000428549200022)，CCR-EXPANDED(收录号:WOS:000428549200022)】；

基金：Project supported by National Key R&D Program of China (2017YFB0306701). We thank Professor Yifeng Chen of East China University of Science and Technology.

语种：英文

摘要：A simple, practical and governable palladium-catalyzed hydroformylation of terminal arylacetylenes has been disclosed. The reaction proceeds under syngas-free conditions, using readily available glyoxylic acid as the formyl source, under mild conditions, giving rise to a broad range of alpha,beta-unsaturated aldehydes.